course-details-portlet

TKP4155 - Reaction Kinetics and Catalysis

About

Examination arrangement

Examination arrangement: School exam
Grade: Letter grades

Evaluation Weighting Duration Grade deviation Examination aids
School exam 100/100 4 hours D

Course content

The course is an introduction to important principles and methods of heterogeneous catalysis. Topics are:

  • The importance of catalysis as a key technology in the chemical process industry, in energy conversion as well as in environmental chemistry processes.
  • Definition of catalysis, elementary reactions, and catalytic sequences.
  • Concepts and principles of adsorption, desorption, surface area and porosity.
  • Modern theories for surfaces and surface reactions.
  • Langmuir-Hinshelwood kinetics.
  • Kinetic modelling, including model fitting and data treatment.
  • Internal and external mass and heat transfer in catalyst particles as well as the effect of diffusion on reaction kinetics.
  • Catalyst preparation.
  • Multifunctional catalysis.

Learning outcome

Knowledge:

  • Overview about important industrial catalytic processes and the most common catalysts.
  • Know how catalysts are applied in sustainable industrial processes to reduce the energy demand and to improve selectivity to the desired products.
  • Be able to identify reaction sequences and suggest reaction mechanisms for chemical reactions.
  • Be familiar with methods for preparation of catalysts.
  • Know how internal and external mass transfer limitations influence the kinetics of catalytic reactions.
  • Understand the most common deactivation mechanisms for heterogeneous catalysts and how they influence the kinetics.
  • Be aware of the criteria of good experimental practice in kinetic measurements.
  • Understand Langmuir-Hinshelwood kinetic model development and data treatment.

Skills:

  • Derive rate expressions for catalytic reactions based on Langmuir-Hinshelwood kinetics.
  • Design catalytic experiments with control over reaction kinetics without influence of heat and mass transfer limitations.
  • Apply chemisorption and kinetic data to calculate reaction rates and specific reaction rates.
  • Develop kinetic models for selected chemical reactions.
  • Identify and distinguish different deactivation mechanisms present in heterogeneous catalysts.
  • Identify internal and external mass transfer limitations by using diagnostic criteria.
  • Identify individual elementary reactions.

General competence:

  • Be familiar with the principles of catalytic reactions and how the kinetics of the reactions can be derived and applied in practice.
  • Recognize important catalytic reactions, in particular for energy conversion and environmental chemistry processes.
  • The candidates should be able to identify if a reaction is kinetically controlled or if it is controlled by external limitations such as heat or mass transfer.

Learning methods and activities

The course is given as 3 hours of lectures, 2 hours of of exercises and 7 hours of self study per week. 7 exercises must be passed in order to be admitted to the exam. A score of 60% or higher must be achieved for passing an exercise. Lectures and exam are given in English.

Compulsory assignments

  • Exercises

Further on evaluation

If there is a re-sit examination, the examination form may change from written to oral.

Course materials

I. Chorkendorff and J. W. Niemantsverdriet: Concepts of Modern Catalysis and Kinetics, 3rd edition

Credit reductions

Course code Reduction From To
SIK2060 7.5
KP8903 7.5 AUTUMN 2010
More on the course

No

Facts

Version: 1
Credits:  7.5 SP
Study level: Second degree level

Coursework

Term no.: 1
Teaching semester:  AUTUMN 2024

Language of instruction: English

Location: Trondheim

Subject area(s)
  • Technological subjects
Contact information
Course coordinator: Lecturer(s):

Department with academic responsibility
Department of Chemical Engineering

Timetable

List view
Calendar view

Examination

Examination arrangement: School exam

Term Status code Evaluation Weighting Examination aids Date Time Examination system Room *
Autumn ORD School exam 100/100 D 2024-11-30 09:00 INSPERA
Room Building Number of candidates
SL520 Sluppenvegen 14 33
SL510 Sluppenvegen 14 35
Summer UTS School exam 100/100 D INSPERA
Room Building Number of candidates
  • * The location (room) for a written examination is published 3 days before examination date. If more than one room is listed, you will find your room at Studentweb.
Examination

For more information regarding registration for examination and examination procedures, see "Innsida - Exams"

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